Ion‐Pair Theory of Concentrated Electrolytes. IV. Ion Atmosphere Charge Distribution
نویسندگان
چکیده
منابع مشابه
Charge neutrality breakdown in confined aqueous electrolytes: Theory and simulation.
We study, using Density Functional theory (DFT) and Monte Carlo simulations, aqueous electrolyte solutions between charged infinite planar surfaces, in contact with a bulk salt reservoir. In agreement with recent experimental observations [Z. Luo et al., Nat. Commun. 6, 6358 (2015)], we find that the confined electrolyte lacks local charge neutrality. We show that a DFT based on a bulk-HNC expa...
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 1971
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.1675357